The Clarets møter Port Vale i sesongens første Capital One cupens første runde, en motstander de også møtte i 2012/13-sesongen. 

Carlisle United – Chesterfield

Nottingham Forest – Walsall

Fleetwood Town – Hartlepool United

Scunthorpe United – Barnsley

Bolton Wanderers – Burton Albion

Accrington Stanley – Hull City

Rochdale – Coventry City

Oldham Athletic – Middlesbrough

Huddersfield Town – Notts County

Blackburn Rovers – Shrewsbury Town

Morecambe – Sheffield United

Doncaster Rovers – Leeds United

Wigan Athletic – Bury

Northampton Town – Blackpool

Sheffield Wednesday – Mansfield Town

Rotherham United – Cambridge United

Crewe Alexandra – Preston North End

York City – Bradford City

Port Vale – Burnley

Peterborough United – Crawley Town

Yeovil Town – Queens Park Rangers

Plymouth Argyle – Gillingham

Swindon Town – Exeter City

Bristol Rovers – Birmingham City

Ipswich Town – Stevenage

Luton Town – Bristol City

Charlton Athletic – Dagenham & Redbridge

Wolverhampton Wanderers – Newport County

Brentford – Oxford United

Portsmouth – Derby County

Southend United – Brighton & Hove Albion

Milton Keynes Dons – Leyton Orient

Cardiff City – AFC Wimbledon

Millwall – Barnet

Wycombe Wanderers – Fulham

Colchester United – Reading